A solution was prepared by dissolving 1210 mg of K_{3}Fe(CN)_{6} (329.2 g/mol) in sufficient waterto give 775 mL. Calculate: a) the molar analytical c

boitshupoO

boitshupoO

Answered question

2020-12-12

A solution was prepared by dissolving 1210 mg of K3Fe(CN)6 (329.2 g/mol) in sufficient waterto give 775 mL. Calculate:
a) the molar analytical concentration of K3Fe(CN)6.
b) the molar concentration of K+.
c) the molar concentration of Fe(CN)63.
d) the weight/volume percentage of K3Fe(CN)6.
e) the number of millimoles of K+ in 50.0 mL of thissolution
f) ppm Fe(CN)63.
g) pK for the solution
h) pFe(CN)6 for the solution.

Answer & Explanation

krolaniaN

krolaniaN

Skilled2020-12-13Added 86 answers

I am using ur calculated value
Molarity of Fe(CN)63=4.74103 M
Moles = molarity * V(L)
=4.74103M0.775L=3.674103 mol
Mass of Fe(CN)63 = moles * molar mass of Fe(CN)63
=3.674103 mol * 212.0 g/mol
= 0.7788g
ppm = mass of solute / mass of solution 106
= 0.7788g / 775 g 106 (for water 1ml = 1g)
= 1005 ppm
= 1.005 mg/ L
Hope its clear to U!
for the molarity of Fe(CN)63. , i got 4.74x103 M

Jeffrey Jordon

Jeffrey Jordon

Expert2021-10-08Added 2605 answers

(a):

Given values:

Mass of K3Fe(CN)6=1210mg=1.210g             (Conversion factor: 1 g = 1000 mg)

Molar mass of K3Fe(CN)6=329.2g/mol

Volume of solution = 775 mL

Plugging values in equation 1:

 

Molarity of K3Fe(CN)6=1.210×1000329.2×775

 

Molarity of K3Fe(CN)6=0.0047M

b)

The equation for the dissociation of K3Fe(CN)6 into its ions follows:

K3Fe(CN)6(aq)3K+(aq)+Fe(CN)63(aq)

1 mole of K3Fe(CN)6 produces 3 moles of K^+ ions and 1 mole of Fe(CN)63 ion

 

Molar concentration of K+ ions=(3×0.0047)=0.0141M

c)

 

Molar concentration of Fe(CN)63 ions=(1×0.0047)=0.0047M

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