Why can a system extract heat from an environment at constant temperature for free?

Dean Summers

Dean Summers

Answered question

2022-07-16

Why can a system extract heat from an environment at constant temperature for free?

Answer & Explanation

Cheyanne Charles

Cheyanne Charles

Beginner2022-07-17Added 13 answers

Assume that the surroundings are infinitely large and at temperature T , and that the system and surroundings are in thermal contact
If the system is at T > T then there will be spontaneous heat transfer from the system to the surroundings until the system reaches T
If the system is at T < T then there will be spontaneous heat transfer from the surroundings to the system until the system reaches T
This heat energy comes "for free" in that it is given to/taken from the system all by itself. The experimenter doesn't need to give or accept any energy to help the system reach equilibrium.
Note that it's not possible to heat the system above T (or cool it below T ) "for free." The only change that is "free" is bringing the system to T and keeping it there.

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