How to derive an expression for entropy in form of S=ln omega from the form S=−sum_i p_i lnp_i ?

badlife18va

badlife18va

Answered question

2022-08-12

How to derive an expression for entropy in form of
S = ln Ω
from the form
S = i p i ln p i ?

Answer & Explanation

kunstdansvo

kunstdansvo

Beginner2022-08-13Added 16 answers

If there are Ω states and p i is constant by the fundamental postulate of statistical mechanics, then you have
1 = i = 1 Ω   p i = Ω   p i         p i = 1 Ω ,
and consequently
S = i = 1 Ω   p i ln p i = i = 1 Ω   p i ln 1 Ω = ( ln 1 Ω ) i = 1 Ω   p i = ln Ω .

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